Determining Ka by the Half-Titration of a Weak Acid
Experiment #24 from Advanced Chemistry with Vernier
Introduction
A common analysis of a weak acid or a weak base is to conduct a titration with a base or acid of known molar concentration to help determine the equilibrium constant, Ka, for the weak acid or weak base. If this titration is conducted very carefully and very precisely, the results can lead to a valid approximation of an equilibrium constant. In this experiment, however, you will use a different technique to determine the Ka for a weak acid, acetic acid.
Your primary goal in this experiment is to calculate the Ka of acetic acid. The data that you will use to complete your calculations will come from the reaction of acetic acid with a solution of NaOH. Recall from your work with weak acid-strong base titrations that the point at which a reaction is half-titrated can be used to determine the pKa of the weak acid. In this experiment, the half-titration point will exist when you have added half as many moles of HC2H3O2 as moles of NaOH . Thus, OH– will have reacted with half of the HC2H3O2, leaving the solution with equal moles of HC2H3O2 and C2H3O2–. At this point, according to the Henderson-Hasselbalch equation,
![pH = p{K_a} + \log \frac{{[{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{3}}}{\text{O}}_{\text{2}}^ - ]}} {{[{\text{H}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{3}}}{{\text{O}}_{\text{2}}}]}}](https://s0.wp.com/latex.php?latex=pH+%3D+p%7BK_a%7D+%2B+%5Clog+%5Cfrac%7B%7B%5B%7B%7B%5Ctext%7BC%7D%7D_%7B%5Ctext%7B2%7D%7D%7D%7B%7B%5Ctext%7BH%7D%7D_%7B%5Ctext%7B3%7D%7D%7D%7B%5Ctext%7BO%7D%7D_%7B%5Ctext%7B2%7D%7D%5E+-+%5D%7D%7D++%7B%7B%5B%7B%5Ctext%7BH%7D%7D%7B%7B%5Ctext%7BC%7D%7D_%7B%5Ctext%7B2%7D%7D%7D%7B%7B%5Ctext%7BH%7D%7D_%7B%5Ctext%7B3%7D%7D%7D%7B%7B%5Ctext%7BO%7D%7D_%7B%5Ctext%7B2%7D%7D%7D%5D%7D%7D&bg=ffffff&fg=000000&s=2 "pH = p{K_a} + \log \frac{{[{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{3}}}{\text{O}}_{\text{2}}^ - ]}} {{[{\text{H}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{3}}}{{\text{O}}_{\text{2}}}]}}")
if there are equal moles of HC2H3O2 and C2H3O2– at the half-titration point, then pKa is equal to the pH value of the solution.
Objectives
In this experiment, you will
- Conduct a reaction between solutions of a weak acid and sodium hydroxide.
- Determine the half-titration point of an acid-base reaction.
- Calculate the pKa and the Ka for the weak acid.
Sensors and Equipment
This experiment features the following sensors and equipment. Additional equipment may be required.
Option 1
Option 2
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This experiment is #24 of Advanced Chemistry with Vernier. The experiment in the book includes student instructions as well as instructor information for set up, helpful hints, and sample graphs and data.
