For most dissolved oxygen testing, it is not necessary to compensate for salinity. However, when measuring dissolved oxygen concentration in highly saline water (>1 part per thousand salinity), the calibration value entered into the software for air-saturated water (from standard tables) should be adjusted. To determine the adjusted value, use the formula:
DO(salt) = DO – (k*S)
Where:
– DO(salt) is the dissolved oxygen concentration (in mg/L) of air-saturated salt water.
– DO is the dissolved oxygen concentration (in mg/L) of air-saturated distilled water as determined from standard tables (found in the sensor’s user manual).
– S is the salinity value (in parts per thousand) of the sample.
– k is a constant. The value of k varies according to the sample temperature, and can be determined from the table below.
Salinity correction constant values
Temp (°C) | Constant, k |
---|---|
1 | 0.08796 |
2 | 0.08485 |
3 | 0.08184 |
4 | 0.07911 |
5 | 0.07646 |
6 | 0.07391 |
7 | 0.07135 |
8 | 0.06916 |
9 | 0.06697 |
10 | 0.06478 |
11 | 0.06286 |
12 | 0.06104 |
13 | 0.05931 |
14 | 0.05757 |
15 | 0.05602 |
16 | 0.05456 |
17 | 0.05328 |
18 | 0.05201 |
19 | 0.05073 |
20 | 0.04964 |
21 | 0.04854 |
22 | 0.04754 |
23 | 0.04662 |
24 | 0.0458 |
25 | 0.04498 |
26 | 0.04425 |
27 | 0.04361 |
28 | 0.04296 |